Environment & Energy
Related: About this forumBioavailability and Toxicity of Critical Metals: A Focus on Indium and Zinc.
The paper to which I'll refer in this post is this one: A Multidisciplinary Approach That Considers Occurrence, Geochemistry, Bioavailability, and Toxicity to Prioritize Critical Minerals for Environmental Research, Sarah Jane O. White, Tyler J. Kane, Kate M. Campbell, Marie-Noële Croteau, Michael Iacchetta, Johanna M. Blake, Charles A. Cravotta III, Bethany K. Kunz, Charles N. Alpers, Jill A. Jenkins, and Katherine Walton-Day, Environmental Science & Technology 2024 58 (51), 22519-22527
The article is open sourced; anyone can read it.
It caught my eye because there used to be a dumb person around here, a rote antinuke, who wanted to carry on about how the supply of indium was so large that we could cover all the deserts in the US with CIGS (cadmium-indium-gallium selenide) solar cells, this in response to my claim that the solar industry - which has been useless in addressing the extreme global heating - faces materials limitations. I pointed to indium, a relatively rare element that is generally found as an impurity in zinc ores. (The indium fraction used to be discarded as mine tailings; these tailings are now considered a resource for the element, which has important uses in electronics, in particular touch screens, in the form of ITO, indium tin oxide.)
It is probably the case that CIGS solar cells are nowhere near as toxic as cadmium telluride solar cells might prove to be, a subject on which I touched here recently:
Comparing the Desert Sun Solar Facility with Diablo Canyon Nuclear Plant: Energy, Cost, and Land Area.
Pedro Amado Petroli, Priscila Silva Silveira Camargo, Rodrigo Andrade de Souza, Hugo Marcelo Veit, Assessment of toxicity tests for photovoltaic panels: A review, Current Opinion in Green and Sustainable Chemistry, Volume 47, 2024, 100885
From the article's conclusions:
The person who used to access geological survey web pages to say that the world will never run out of indium may still be here; I don't know; I have an extensive "ignore list" here.
To me, it doesn't matter whether there is enough indium to create a putative promised but never realized so called "renewable energy" nirvana. I oppose the solar industry on the environmental grounds that its mineral and land requirements are odious, and that the expenditure of trillions of dollars on it has had no result other than to make the collapse of the planetary atmosphere accelerate.
The Disastrous 2024 CO2 Data Recorded at Mauna Loa: Yet Another Update 12/08/2024
Anyway, again, the paper is open sourced, anyone can read it. Some excerpts for convenience:
Because the U.S. Critical Minerals list (2) originates from a legislative mandate, critical minerals is a general term that is not strictly technical. The list includes a combination of elements and minerals; for this research prioritization effort, for tractability, we will discuss the primary element of interest associated with each mineral and will refer to them as critical elements (Table S1).
Increasing recovery and use of critical elements can enhance mobilization, environmental distribution, and exposures, with unexplored or unanticipated effects on biota and ecosystem health. For example, mineral extraction and processing often increase initial element concentrations by orders of magnitude in recovered concentrates or wastes, compounding the potential for harmful environmental release and exposure. However, the effects of increased exposures are difficult to predict because of substantial data gaps in geochemistry, bioavailability, and toxicity for many critical elements. At the same time, understanding the behavior of critical elements during processing and in wastes is the first step in improving their recovery and minimizing environmental impact. Given the large number of critical elements (∼50 on the most recent U.S. list (Table S1)) and the growing urgency to increase production, how do governments, regulators, scientists, and industries identify research priorities to help ensure that critical elements are recovered, refined, used, reused, and disposed in a sustainable, environmentally responsible manner?
A few studies have prioritized elements for research based on a single topic area (e.g., criticality, health impacts) using criteria such as geographic origin of current supplies, availability of alternative resources, anthropogenic disturbance of natural elemental cycles, and data availability for biomarkers and health impacts. For example, in determining which elements should be placed on the U.S. Critical Minerals list, Nassar et al. (1,8) developed metrics for essentiality and vulnerability to supply chain disruption by which they could prioritize criticality...
...More than 1,200 publications published through March 2023 were categorized into 11 review categories (Figure 2 and SI References). Of the critical elements considered, zinc had the 14th highest number of reviews (49), and indium the 34th highest (22). This ranking would elevate indiums priority for study (Figure 3). There are more zinc reviews focused on Bioavailability/Toxicity than any other category, whereas the Geochemistry/Geology category was dominant for indium. Both elements are missing representation in the Microorganisms category, which encompasses reviews focused predominantly on microbial-element interactions. The distribution of review articles across the critical elements likely has been driven by factors such as known human and environmental health effects, technological and industrial use, as well as historic economic value...
A graphic from the paper:
The caption:
Happy New Year, even if 2025 is going to be, in my opinion, a form of hell.
eppur_se_muova
(37,758 posts)If any CIGS cells are destroyed by burning, I wouldn't want to be within miles of that smoke. Same with anything containing cadmium.
Oooh, on further reading it turns out that most CIGS cells are capped with a "buffer" layer of CdS (WHY CdS I don't know). So toxic cadmium AND toxic selenium in one delightful sandwich.
https://en.wikipedia.org/wiki/Selenium#Toxicity
https://en.wikipedia.org/wiki/Cadmium_poisoning
NNadir
(34,881 posts)...the alternative of placing them on rooftops on combustible buildings makes this toxicity issue a very real concern, since even the ashes of the fires will be toxicological issues in the form of distributed pollution. This is especially an issue where large suburban fires at the edges of forests or grasslands take place and a large number of houses burn. We are seeing more and more of this sort of thing, particularly because of droughts driven by extreme global heating.
Cadmium ores are often sulfides, and the way to liberate cadmium is often by roasting, so the risks are clear.
There is evidence of toxicology associated with indium, chiefly represented as lung pathology.
Among many papers on the subject, which I pulled up at random among many, there is this: I-Jen Chang, Chuan-Yen Sun, Wei-Chih Chen, Ting-An Yang, Hao-Yi Fan, Yang-Chieh Brian Chen, Yu-Chung Tsao,Associations between serum indium levels and preserved ratio impaired spirometry among non-smoking industrial workers: A nationwide cross-sectional study in Taiwan Respiratory Medicine, Volume 236, 2025, 107908.
Most of the studies associated with lung disease focus on indium tin oxide (ITO) so it is not clear that indium in solar cells would have the same issues, but neither can it be ruled out.