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NNadir

(34,881 posts)
Sat Dec 28, 2024, 09:43 AM Dec 28

Bioavailability and Toxicity of Critical Metals: A Focus on Indium and Zinc.

The paper to which I'll refer in this post is this one: A Multidisciplinary Approach That Considers Occurrence, Geochemistry, Bioavailability, and Toxicity to Prioritize Critical Minerals for Environmental Research, Sarah Jane O. White, Tyler J. Kane, Kate M. Campbell, Marie-Noële Croteau, Michael Iacchetta, Johanna M. Blake, Charles A. Cravotta III, Bethany K. Kunz, Charles N. Alpers, Jill A. Jenkins, and Katherine Walton-Day, Environmental Science & Technology 2024 58 (51), 22519-22527

The article is open sourced; anyone can read it.

It caught my eye because there used to be a dumb person around here, a rote antinuke, who wanted to carry on about how the supply of indium was so large that we could cover all the deserts in the US with CIGS (cadmium-indium-gallium selenide) solar cells, this in response to my claim that the solar industry - which has been useless in addressing the extreme global heating - faces materials limitations. I pointed to indium, a relatively rare element that is generally found as an impurity in zinc ores. (The indium fraction used to be discarded as mine tailings; these tailings are now considered a resource for the element, which has important uses in electronics, in particular touch screens, in the form of ITO, indium tin oxide.)

It is probably the case that CIGS solar cells are nowhere near as toxic as cadmium telluride solar cells might prove to be, a subject on which I touched here recently:

Comparing the Desert Sun Solar Facility with Diablo Canyon Nuclear Plant: Energy, Cost, and Land Area.

Someday all of this garbage, at quantities of millions of tons, will need to be hauled away:

Pedro Amado Petroli, Priscila Silva Silveira Camargo, Rodrigo Andrade de Souza, Hugo Marcelo Veit, Assessment of toxicity tests for photovoltaic panels: A review, Current Opinion in Green and Sustainable Chemistry, Volume 47, 2024, 100885

From the article's conclusions:

This review has shown that the solar cell technologies most readily found on the market contain hazardous metals and rare metals. In addition, this review has shown concern associated with the toxicity and waste disposal of PV modules; all the articles used in this review showed that PVs should be considered hazardous, indicating hazardous waste landfill disposal if recycling is not feasible.



The person who used to access geological survey web pages to say that the world will never run out of indium may still be here; I don't know; I have an extensive "ignore list" here.

To me, it doesn't matter whether there is enough indium to create a putative promised but never realized so called "renewable energy" nirvana. I oppose the solar industry on the environmental grounds that its mineral and land requirements are odious, and that the expenditure of trillions of dollars on it has had no result other than to make the collapse of the planetary atmosphere accelerate.

The Disastrous 2024 CO2 Data Recorded at Mauna Loa: Yet Another Update 12/08/2024

Anyway, again, the paper is open sourced, anyone can read it. Some excerpts for convenience:

Critical minerals are essential to national and global security and prosperity, with supply chains vulnerable to disruption. (1) The 2022 Critical Minerals list for the United States (U.S.) (2) identifies 50 mineral commodities, of which rare-earth elements (REE), platinum group metals (PGM), and indium are most frequently identified as critical, globally. (3) Other countries also have critical minerals lists, with overlapping and contrasting commodities to the United States. (3) These commodities are associated with elements across the periodic table, and are used in a wide array of applications, including green energy, communications, defense, and consumer electronics. Yet for many of the critical minerals, only limited information is available about environmental occurrence, distribution, mobility, and potential adverse effects on ecosystem and biota health.e.g. (4−7)

Because the U.S. Critical Minerals list (2) originates from a legislative mandate, “critical minerals” is a general term that is not strictly technical. The list includes a combination of elements and minerals; for this research prioritization effort, for tractability, we will discuss the primary element of interest associated with each mineral and will refer to them as “critical elements” (Table S1).
Increasing recovery and use of critical elements can enhance mobilization, environmental distribution, and exposures, with unexplored or unanticipated effects on biota and ecosystem health. For example, mineral extraction and processing often increase initial element concentrations by orders of magnitude in recovered concentrates or wastes, compounding the potential for harmful environmental release and exposure. However, the effects of increased exposures are difficult to predict because of substantial data gaps in geochemistry, bioavailability, and toxicity for many critical elements. At the same time, understanding the behavior of critical elements during processing and in wastes is the first step in improving their recovery and minimizing environmental impact. Given the large number of critical elements (∼50 on the most recent U.S. list (Table S1)) and the growing urgency to increase production, how do governments, regulators, scientists, and industries identify research priorities to help ensure that critical elements are recovered, refined, used, reused, and disposed in a sustainable, environmentally responsible manner?

A few studies have prioritized elements for research based on a single topic area (e.g., criticality, health impacts) using criteria such as geographic origin of current supplies, availability of alternative resources, anthropogenic disturbance of natural elemental cycles, and data availability for biomarkers and health impacts. For example, in determining which elements should be placed on the U.S. Critical Minerals list, Nassar et al. (1,8) developed metrics for essentiality and vulnerability to supply chain disruption by which they could prioritize criticality...

...More than 1,200 publications published through March 2023 were categorized into 11 review categories (Figure 2 and SI References). Of the critical elements considered, zinc had the 14th highest number of reviews (49), and indium the 34th highest (22). This ranking would elevate indium’s priority for study (Figure 3). There are more zinc reviews focused on “Bioavailability/Toxicity” than any other category, whereas the “Geochemistry/Geology” category was dominant for indium. Both elements are missing representation in the “Microorganisms” category, which encompasses reviews focused predominantly on microbial-element interactions. The distribution of review articles across the critical elements likely has been driven by factors such as known human and environmental health effects, technological and industrial use, as well as historic economic value...


A graphic from the paper:



The caption:

Figure 2. Review papers published through March 2023 for each of the critical elements listed on the 2018 and 2022 U.S. Critical Minerals lists (2,20) (Table S1), arranged by category defined by this study. A complete list of references for this figure are in the SI, obtained from the Web of Science Core Collection database.


Happy New Year, even if 2025 is going to be, in my opinion, a form of hell.
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Bioavailability and Toxicity of Critical Metals: A Focus on Indium and Zinc. (Original Post) NNadir Dec 28 OP
Whoopsie, the "C" in CIGS is for copper. But hey, selenium is plenty toxic enough. eppur_se_muova Sunday #1
The risk of fires in desert ecosystems rendered into industrial parks for solar facilities is probably low, but... NNadir Sunday #2

eppur_se_muova

(37,758 posts)
1. Whoopsie, the "C" in CIGS is for copper. But hey, selenium is plenty toxic enough.
Sun Dec 29, 2024, 05:08 PM
Sunday

If any CIGS cells are destroyed by burning, I wouldn't want to be within miles of that smoke. Same with anything containing cadmium.

Oooh, on further reading it turns out that most CIGS cells are capped with a "buffer" layer of CdS (WHY CdS I don't know). So toxic cadmium AND toxic selenium in one delightful sandwich.

https://en.wikipedia.org/wiki/Selenium#Toxicity
https://en.wikipedia.org/wiki/Cadmium_poisoning

NNadir

(34,881 posts)
2. The risk of fires in desert ecosystems rendered into industrial parks for solar facilities is probably low, but...
Sun Dec 29, 2024, 06:17 PM
Sunday

...the alternative of placing them on rooftops on combustible buildings makes this toxicity issue a very real concern, since even the ashes of the fires will be toxicological issues in the form of distributed pollution. This is especially an issue where large suburban fires at the edges of forests or grasslands take place and a large number of houses burn. We are seeing more and more of this sort of thing, particularly because of droughts driven by extreme global heating.

Cadmium ores are often sulfides, and the way to liberate cadmium is often by roasting, so the risks are clear.

There is evidence of toxicology associated with indium, chiefly represented as lung pathology.

Among many papers on the subject, which I pulled up at random among many, there is this: I-Jen Chang, Chuan-Yen Sun, Wei-Chih Chen, Ting-An Yang, Hao-Yi Fan, Yang-Chieh Brian Chen, Yu-Chung Tsao,Associations between serum indium levels and preserved ratio impaired spirometry among non-smoking industrial workers: A nationwide cross-sectional study in Taiwan Respiratory Medicine, Volume 236, 2025, 107908.

Most of the studies associated with lung disease focus on indium tin oxide (ITO) so it is not clear that indium in solar cells would have the same issues, but neither can it be ruled out.

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